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Booster Technology for Hydrogen Compression – Challenges and Solutions

机译:氢气压缩的增强技术 - 挑战和解决方案

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Fuel cell driven vehicles operated with compressed hydrogen are typically using composite cylinders in order to store the gas at pressures of up to 700 bar. The supply of hydrogen in the required volume and pressure is the logistical challenge of every filling station since the gas has to be transferred and compressed with minimal use of energy. However, the technical challenges are sometimes not noticed and should be looked at in this paper. The compression technology we are looking at is the reciprocating air driven booster. They are an economical alternative to electrical driven compressors and comply with the explosion proof directive 94/9/EC in the category 2G/2D, group IIC. Boosters used for filling station pressures of up to 700 bar are typically operated in different stages up to 1000 bar in order to enable an adequate differential pressure. At these pressures materials with high yield strengths (Rp0,2) are required. Austenitic stainless steel of the 316L series as referred to in the IGC document 121/04/E has become a standard for many high pressure hydrogen applications since it shows good resistance against hydrogen embrittlement. The corresponding material code for 1.4404 lists yield strengths of up to 320 MPa [1] which can be improved by cold working to values of about 750 MPa [2]. Since one of the limiting factors for the cold working process is the dimension, different solutions have to be found when the available mechanical properties are not sufficient. For the final compression stage of a typical booster station the standard material comes to its limits according to the FEM analysis and the use of cold worked material is not possible because of the diameter and the limitation of cold working. An alternative material suitable for hydrogen with yield strengths of greater 500 MPa is required and found with the creep resistant steel 1.4980. The material has a yield strength (Rp0,2) of 600 MPa [3] and a high nickel content of 25.3% [3] which meets the mechanical requirements plus those of the Japanese KHK regulation which opens a new geographical target market.
机译:用压缩氢操作操作的燃料电池驱动车辆通常使用复合汽缸,以将气体储存在高达700巴的压力下。在所需的体积和压力下供应氢是每个灌装站的后勤挑战,因为必须通过最小的能量来转移和压缩气体。然而,有时没有注意到技术挑战,应该看看本文。我们正在寻找的压缩技术是往复的空气驱动助推器。它们是电动驱动压缩机的经济替代方案,并符合2G / 2D组IIC类别中的防爆指令94/9 / EC。用于灌装站压力最多700巴的助推器通常在不同的阶段运行,最高可达1000栏,以便能够实现足够的差压。在这些压力下,需要高屈服强度(RP0,2)。 IGC文件121/04 / E中所提及的316L系列的奥氏体不锈钢已成为许多高压氢应用的标准,因为它显示出良好的抗氢脆性抗性。 1.4404的相应材料代码列出了高达320MPa [1]的屈服强度,可以通过冷工作至约750MPa的值来改善。由于冷工作过程的一个限制因素是尺寸,因此当可用的机械性能不足时,必须找到不同的解决方案。对于典型的增压站的最终压缩阶段,标准材料根据有限元分析,由于直径和冷加工的限制,不可能使用冷加工材料的使用。需要具有屈服强度较大500MPa的氢的替代材料,并用抗蠕变钢1.4980发现。该材料具有600MPa [3]的屈服强度(RP0,2),高镍含量为25.3%[3],符合机械要求加上日本KHK调节的含量,该标准开启了新的地理目标市场。

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