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Gasification of Torrefied and Soft Wood Pellets in Air and CO_2

机译:空气和CO_2中烘焙和软木颗粒的气化

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This paper examines the gasification of woody biomass pellets and torrefied wood pellets at different temperatures using air or CO_2 as the gasifying agents. The woody biomass pellets were pyrolyzed and gasified in a controlled reactor facility that allowed for the determination of sample weight loss as a function of time from which the kinetics parameters were evaluated. The experimental facility provided full optical access that allowed for in-situ monitoring of the fate of the biomass pellets and the release of gas phase under prescribed high temperature condition. Pellet sample of known weight was placed in a wire mesh cage and then introduced instantly into the high temperature zone of the reactor at known temperature and surrounding gas composition as gasifying agent. The weight loss as function of time was examined for different gasification temperatures ranging from 600-950°C using air or CO_2 as the gasifying agent. Significant differences in the weight loss were observed to reveal the fundamental pyro-gasification behavior between the wood and torrefied wood pellets. The results show enhanced gasification with air at low to moderate temperatures while at high temperatures the oxygen evolved from CO_2 provided a role in oxidation. The calculated activated energy was lower for woody pellets than torrefied wood pellets and it was lower with air than CO_2. These kinetic parameters help in modeling to design biomass gasifiers and combustors for increased conversion efficiency and performance using biomass or municipal solid waste pellets.
机译:本文探讨木质生物质颗粒和在使用空气或CO_2作为气化剂不同的温度下焙烧过的木材颗粒的气化。所述木质生物质颗粒热解和在受控的反应器设施气化,允许对样品重量损失的测定从该动力学参数进行了评价的时间的函数。实验设施提供,允许用于原位监测的生物质颗粒的命运和气相的规定的高温度条件下释放的全光接入。已知重量的丸粒样品置于金属丝网笼,然后立即导入到在已知温度下的反应器的高温区和气体组成周围作为气化剂。检验了不同的气化温度下使用空气或CO_2作为气化剂从600-950℃下的重量损失作为时间的函数。观察在减肥显著差异揭示木材和烘焙木屑颗粒之间的根本焦气化行为。结果表明在低的增强用空气气化至适中的温度,同时在高温下从CO_2放出的氧提供在氧化的作用。所计算的活化能是为木质粒料比烘焙木颗粒下,它是与空气比CO_2低。这些动力学参数帮助造型设计生物质气化和燃烧器使用生物质或城市固体废物的颗粒提高转换效率和性能。

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