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Fabrication and characterization of Mn doped ZnO nanoarrays prepared by two step process

机译:两步法制备Mn掺杂ZnO纳米阵列的制造与表征

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In this paper we have synthesized thin films of undoped and Mn doped ZnO samples with varying Mn percentage (2% at.wt., 4% at.wt., 6% at.wt.) by two step process i.e. sol-gel and hydrothermal process. This study reported the structural, surface, optical and electrical properties of the samp les by using XRD, FESEM, UV-vis spectroscopy and Keithley instruments. The XRD spectra confirms that all the prepared thin films have hexagonal wurtzite structure, the cell parameters increase with the increase of doping concentration, confirming the Mn substitution into the host lattice. Red shift of the UV emission has occurred in all the doped samples is attributed to decrease in particle size and increase in the concentration of oxygen vacancies on ZnO surface, these defect levels are also confirmed by PL. The electrical characteristic shows increase in conductivity with rise in doping concentration in ZnO.
机译:在本文中,我们已经合成了未掺杂的和Mn掺杂的ZnO样品的薄膜,其百分比(2%为2%,4%,at.wt.,6%.wt.),即溶胶 - 凝胶和溶胶 - 凝胶 水热过程。 本研究报告了SAMP LES的结构,表面,光学和电性能通过使用XRD,FESEM,UV-Vis光谱和Keithley仪器。 XRD光谱确认所有制备的薄膜都具有六边形紫硝基钛矿结构,细胞参数随着掺杂浓度的增加而增加,证实Mn替换到主晶格中。 在所有掺杂的样品中发生UV发射的红色偏移归因于粒度降低和ZnO表面上氧空位浓度的增加,这些缺陷水平也通过PL确认。 电学特性显示导电性增加,ZnO中掺杂浓度升高。

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