Selective Synthesis of Hetero-multinuclear Metal Complexes byusing Symmetrical and Unsymmetrical Porphyrin Ligands

摘要

Hetero-multinuclear metal complexes are a promising class of compounds havinginteresting properties such as photoluminescence,magnetism,and catalysis.Typicalsynthetic methods to construct hetero-multinuclear complexes are to introduce two kinds ofcoordination sites having a different coordination ability,or to use an inert metal complex asa metalloligand.However,it is still challenging to construct heterometallic complexes byusing two (or more) kinds of metal ions having an analogous coordination property.Herein,we report the selective synthesis of hetero-multinuclear metal complexes based onsymmetric and unsymmetrical porphyrin ligands.