Syntheses of Structurally Well-defied Polycyclic Aromatic Hydrocarbons by One Pot Cascade Reaction of the Suzuki-Miyaura and the Mizoroki-Heck Coupling Reactions

摘要

Polycyclic aromatic hydrocarbons (PAHs) are key component of modern advanced materials such as field effect transistor (FET) and molecule based superconductor. The synthesis of structurally well-defined PAHs is a challenge of chemistry. The oxidative coupling reaction and photocyclization of oligophenylenes represent synthetic methods of PAHs. In this study, we propose a more convenient one-pot cascade reaction involving Suzuki coupling and Mizoroki-Heck coupling reaction.