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Polystyrene-Supported Formate Catalyst for Transformative Reduction of Carbon Dioxide to Formic Acid with Silanes

机译：聚苯乙烯负载甲酸酯催化剂，用于用硅烷转化二氧化碳与甲酸的转化

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摘要

Organic salt of alkylammonium formate supported by polystyrene-divinylbenzene copolymer modified from anion exchange resins exhibited good activity towards transformative reduction of carbon dioxide (CO2) with silanes as reductant (CO2 hydrosilylation) to silylformate.

机译：由来自阴离子交换树脂改性的聚苯乙烯 - 二乙烯基苯共聚物支持的烷基甲酸甲酯的有机盐表现出良好的活性朝向硅烷（CO2氢硅烷化）与硅烷氧化物转化为硅烷化的二氧化碳（CO2）的良好活性。

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《日本化学会春季年会講演予稿集》|2018年|1 CD-ROM|共1页
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Ria Ayu Pramudita; Chihiro Nakagawa; Yuichi Manaka;
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中图分类石油化学工业;
关键词
Carbon Dioxide Reduction; Hydrosilylation; Formic Acid; Organocatalyst; Heterogeneous Catalyst;

机译：二氧化碳减少;氢综合甲硅烷化;甲酸;有机催化剂;异质催化剂;

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专利

1. A Well-Defined Iron Catalyst for the Reduction of Bicarbonates and Carbon Dioxide to Formates, Alkyl Formates, and Formamides† [J] . Christopher Federsel, Albert Boddien, Dr. Ralf Jackstell, Angewandte Chemie International Edition . 2010,第50期

机译：定义明确的铁催化剂，可将碳酸氢盐和二氧化碳还原为甲酸酯，烷基甲酸酯和甲酰胺†
2. A Well-Defined Iron Catalyst for the Reduction of Bicarbonates and Carbon Dioxide to Formates, Alkyl Formates, and Formamides [J] . Christopher Federsel, Albert Boddien, Ralf Jackstell Angewandte Chemie . 2010,第50期

机译：定义明确的铁催化剂，用于将碳酸氢盐和二氧化碳还原为甲酸酯，烷基甲酸酯和甲酰胺
3. Lewis acidic supports promote the selective hydrogenation of carbon dioxide to methyl formate in the presence of methanol over Ag catalysts [J] . Corral-Perez Juan Jose, Coperet Christophe, Urakawa Atsushi Journal of Catalysis . 2019,第期

机译：Lewis酸性载体促进在Ag催化剂上甲醇存在下二氧化碳的选择性氢化到甲酸甲酯
4. Polystyrene-Supported Formate Catalyst for Transformative Reduction of Carbon Dioxide to Formic Acid with Silanes [C] . Ria Ayu Pramudita, Chihiro Nakagawa, Yuichi Manaka 日本化学会春季年会講演予稿集 . 2018

机译：聚苯乙烯负载甲酸酯催化剂，用于用硅烷转化二氧化碳与甲酸的转化
5. New bifunctional catalysts for ammonia-borane dehydrogenation, nitrile reduction, formic acid dehydrogenation, lactic acid synthesis, and carbon dioxide reduction. [D] . Lu, Zhiyao. 2016

机译：用于氨硼烷脱氢，腈还原，甲酸脱氢，乳酸合成和二氧化碳还原的新型双功能催化剂。
6. A highly active non-precious transition metal catalyst for the hydrogenation of carbon dioxide to formates [O] . Benjamin G. Schieweck, Niklas F. Westhues, Jürgen Klankermayer 2019

机译：一种高活性的非贵金属过渡金属催化剂用于二氧化碳加氢生成甲酸酯
7. Progress in inorganic cathode catalysts for electrochemical conversion of carbon dioxide into formate or formic acid [O] . Du, Dongwei, Lan, Rong, Humphreys, John, 2017

机译：用于二氧化碳电化学转化为甲酸或甲酸的无机阴极催化剂的研究进展
8. Formation of a Metal Hydride Bond and the Insertion of CO2. Key Steps in theElectrocatalytic Reduction of Carbon Dioxide to Formate [R] . Pugh, J. R., Bruce, M. R., Sullivan, B. P., 1991

机译：金属氢化物键的形成和CO2的插入。电催化还原二氧化碳到甲酸盐的关键步骤

Polystyrene-Supported Formate Catalyst for Transformative Reduction of Carbon Dioxide to Formic Acid with Silanes

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