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Characterization and integration of oxidation catalysts at small-scale biomass combustion furnaces

机译:小型生物质燃烧炉中氧化催化剂的表征与整合

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Small-scale biomass combustion is a major part in heat supply from renewable resources. Drawbacks to the environmental background are the pollutant emissions, which are formed as a result of maloperation, suboptimal furnace construction or the biomass fuel composition. The named primary factors can be influenced by several measures, but the achievable emission results are limited. To provide real clean combustion technology with nearly zero pollutant emissions, secondary emission reduction measures are necessary. One of these measures is the application of catalytic flue gas cleaning as integrated or downstream solution. Catalysis is already a state of the art element in many processes and following this, some studies reveal already its potential to reduce CO, VOC as well as particle emissions in small-scale biomass combustion systems. However, a wide application of catalysts in wood combustion units didn't take place so far, because the challenging process conditions demand a proper integration and highly stable and active catalytic materials. For the achievement of well-functioning combustion systems with catalyst solutions a procedure for application-oriented characterization is presented. Initial investigations with commercially available catalysts have shown that the gas hourly space velocity and the oxygen content have the most significant influence on the conversion rate of carbon monoxide and nitrogen oxide. Two samples with different active phases have been compared, one with solely metal oxides and one with metal oxides and noble metals. The one with noble metals showed as expected a higher activity, but also a higher stability.
机译:小型生物量燃烧是可再生资源供热的主要部分。对环境背景的缺点是污染物排放,其是由于缺乏恶臭,次优炉结构或生物质燃料组合物而形成的。该命名的主要因素可能受到几种措施的影响,但可实现的发射结果有限。为了提供具有近零污染物排放的真实清洁燃烧技术,需要进行二次排放措施。其中一种措施是在催化烟气清洁作为集成或下游溶液的应用。催化已经是许多过程中的艺术元素的状态,并且在此之后,一些研究表明它已经有可能减少小型生物量燃烧系统中的CO,VOC以及颗粒排放。然而,到目前为止,催化剂在木质燃烧单元中的广泛应用,因为具有挑战性的工艺条件需要适当的整合和高度稳定和活性催化材料。为了实现具有催化剂溶液的功能良好的燃烧系统,提出了一种面向涂备的表征的方法。具有市售催化剂的初始研究表明,气体小时空间速度和氧含量对一氧化碳和氮氧化物的转化率具有最显着的影响。已经比较了具有不同活性阶段的两个样品,一种用单独的金属氧化物和金属氧化物和贵金属。具有贵金属的贵金属的较高活动呈现,也具有更高的稳定性。

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