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Modeling the adsorption of mixed gases based on pure gas adsorption properties

机译:基于纯气吸附性能的混合气体吸附

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Sorption-based Joule-Thomson (JT) cryocoolers usually operate with pure gases. A sorption-based compressor has many benefits; however, it is limited by the pressure ratios it can provide. Using a mixed-refrigerant (MR) instead of a pure refrigerant in JT cryocoolers allows working at much lower pressure ratios. Therefore, it is attractive using MRs in sorption-based cryocoolers in order to reduce one of its main limitations. The adsorption of mixed gases is usually investigated under steady-state conditions, mainly for storage and separation processes. However, the process in a sorption compressor goes through various temperatures, pressures and adsorption concentrations; therefore, it differs from the common mixed gases adsorption applications. In order to simulate the sorption process in a compressor a numerical analysis for mixed gases is developed, based on pure gas adsorption characteristics. The pure gas adsorption properties have been measured for four gases (nitrogen, methane, ethane, and propane) with Norit-RB2 activated carbon. A single adsorption model is desired to describe the adsorption of all four gases. This model is further developed to a mixed-gas adsorption model. In future work more adsorbents will be tested using these four gases and the adsorption model will be verified against experimental results of mixed-gas adsorption measurements.
机译:基于吸附的焦耳 - 汤姆森(JT)冷冻机通常用纯净气体操作。基于吸附的压缩机具有许多益处;但是,它受到它可以提供的压力比的限制。使用混合制冷剂(MR)代替JT冷冻机中的纯制冷剂允许在更低的压力比下工作。因此,使用基于吸附的冷冻剂MRS是有吸引力的,以减少其主要限制之一。混合气体的吸附通常在稳态条件下研究,主要用于储存和分离过程。然而,吸附压缩机中的方法经过各种温度,压力和吸附浓度;因此,它与共同的混合气体吸附应用不同。为了模拟压缩机中的吸附过程,基于纯气体吸附特性,开发了混合气体的数值分析。已经测量纯气体吸附性能,以诺芮特-RB2活性炭测量四个气体(氮气,甲烷,乙烷和丙烷)。希望单一吸附模型描述所有四种气体的吸附。该模型进一步发展到混合气体吸附模型。在未来的工作中,使用这四种气体将测试更多吸附剂,并将验证吸附模型与混合气吸附测量的实验结果进行验证。

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