Nickel Release Rate of Type 303 Free Cutting Austenitic Stainless Steel

摘要

Type 303 austenitic stainless steel has been applied in jewelry production, and its nickel release rate has become a concerned issue in the jewelry industry. In this paper, the commercial type 303 stainless steel was used as the test material, while 304 stainless steel as the contrast material;;their nickel release rates and corrosion behaviors in artificial sweat were studied. The results show that the actually measured nickel release rate of 303 stainless steel reaches 2.06μg/cm~2/week, nearly 25 times higher than that of 304 stainless steel, which exceeds the threshold specified in nickel release standard EN1811:2011 for jewelries coming into direct and prolonged contact with the skin (0.88μg/cm~2/week), and its adjusted value also exceeds the threshold specified in Nickel Directive 2004/96/EC for puncture accessories (0.35μg/cm~2/week). The high nickel release rate for 303 stainless steel is mainly caused by its high sulfur content and the inevitable formation of manganese sulfide inclusions, which will cause the pitting and exacerbate the material corrosion. Considering the risk of nickel sensitization of 303 stainless steel, it is not suggested to use 303 stainless steel as the jewelry material, especially for piercing jewelry.