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Difference in elastic properties of CrB_2 determined by microscopic and macroscopic measurements

机译:通过微观和宏观测量确定CRB_2的弹性特性的差异

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CrB_2 possess the hexagonal AlB_2 structure which belongs to the spacegroup of P6/mmm. The compound exhibits para- to antiferro-magnetic transition at about 88 K. By using a macroscopic measurement technique, that is, a conventional resonant ultrasound spectroscopy (RUS) with a millimeter size mono-crystal, significant elastic anomalies have been observed just above the magnetic transition temperature. On the other hand, elastic constants determined by a microscopic measurement technique, that is, an inelastic X-ray scattering method (BL35XU of SPring-8, Japan) do not show any elastic anomalies at around the transition temperature. In order to explain the discrepancy, we have introduced a kind of so called ΔE effect resulting from a multidomain structure. If crystal lattice is slightly deformed by a spontaneous magnetostriction in the antiferromagnetic state, the symmetry of crystal lattice is lowered from hexagonal to monoclinic when the symmetry of magnetic structure is taken into account. By the lowering of the symmetry, the crystal consists of six magnetic domains in the antiferro magnetic state. If magnetic domain boundaries move in response to externally applied stresses, the mechanical deformation is absorbed by nonelastic deformations induced by the movement of magnetic domain boundaries. This multidomain model well explains the experimental results obtained by both microscopic (X-ray) and macroscopic (ultrasound) measurements. The microscopic measurement technique is useful to obtain the true elastic properties of crystal lattice without effects coming from a multidomain structure.
机译:CRB_2拥有属于P6 / MMM的空间组的六角形ALB_2结构。通过使用宏观测量技术在约88k的情况下表现出对抗散粒磁性转变的验证。即,具有毫米尺寸单晶的常规谐振超声波扫描(RUS),在上方观察到显着的弹性异常。磁化温度。另一方面,通过微观测量技术确定的弹性常数,即,无间质X射线散射方法(Spring-8,日本的BL35xu)不显示出围绕过渡温度的任何弹性异常。为了解释差异,我们已经引入了一种由多域结构产生的所谓的ΔE效应。如果在反铁磁性状态下通过自发磁致伸缩略微变形晶体晶格,则当考虑磁性结构的对称时,晶格从六边形降低到单斜的对称性。通过对称的降低,晶体由六个磁畴组成的抗丝磁态。如果磁畴边界响应于外部施加的应力而移动,则通过磁畴边界的运动引起的非塑性变形吸收机械变形。该多源模型很好地解释了通过微观(X射线)和宏观(超声)测量获得的实验结果。显微镜测量技术可用于获得晶格的真正弹性特性,而不会产生来自多畴结构的效果。

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