Carbon Nanotube Reinforced Metal Matrix Nanocomposites Via Equal Channel Angular Pressing

摘要

Carbon nanotubes (CNTs) have been the subject of intensive study for applications in the fields of nanotechnologies in recent years due to their superior mechanical, electric, optical and electronic properties. Because of their exceptionally small diameters (≈ several nm) as well as their high Young's modulus (≈ 1 TPa), tensile strength (≈ 200 GPa) and high elongation (10-30%) in addition to a high chemical stability, CNTs are attractive reinforcement materials for light weight and high strength metal matrix composites. In this study, bottom-up type powder processing and top-down type SPD (severe plastic deformation) approaches were combined in order to achieve full density of CNT/metal matrix composites with superior mechanical properties by improved particle bonding and least grain growth, which were considered as a bottle neck of the bottom-up method using the conventional powder metallurgy of compaction and sintering. ECAP (equal channel angular pressing), the most promising method in SPD, was used for the CNT/Cu powder consolidation. The powder ECAP processing with 1, 2, 4 and 8 route C passes was conducted at room temperature. It was found by mechanical testing of the consolidated CNT/Cu that high mechanical strength could be achieved effectively as a result of the Cu matrix strengthening and improved particle bonding during ECAP. The ECAP processing of powders is a viable method to achieve fully density CNT-Cu nanocomposites.