Synthesis and Characterization of Tunable and Highly Transparent Thick Layers of Nanocomposites Based on Methacrylates and Silica Nanoparticles

摘要

We present a nanocomposite material based on functionalized silica nanoparticles in a methacrylate matrix. The nanocomposite material is synthesized without addition of a co-solvent, which enables the spin-coating of thick and defect-free layers of several tens of micrometers with smooth surfaces. SEM analysis indicates uniform distribution of the nanoparticles in the methacrylate matrix, and pinhole-free surfaces suitable for applications in optics. For optical characterization, the refractive index of the material for different silica concentrations is reported, and propagation losses in the UV/VIS range discussed. The tuning of the refractive indices can be applied towards the realization of low-loss passive optical waveguides. As a first step towards this goal, the processability of the nanocomposite material for microfluidic applications, and the realization of a planar optical waveguide are demonstrated.