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Effect of Pyrolysis Temperature and Time on Properties of Palm Kernel Shell-Based Biochar

机译:热解温度和时间对棕榈仁壳基生物炭性能的影响

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Pyrolysis is a thermal decomposition of biomass occurring in the absence of oxygen. Biochar (solid), bio-oil (liquid) and biogas (gas) are the typical products from pyrolysis of biomass. This endothermic process produced biochar with high carbon content. During pyrolysis, the material is heated up from ambient to a peak temperature and remains for a defined residence time. Therefore, the pyrolysis peak temperature and the residence time are the key parameters for pyrolysis. Studies on the effect of these parameters on the biochar characteristics and the pyrolysis products composition are numerous. However, there are limited findings of these parameters with palm kernel shell (PKS) as the biomass. This study focusses on the effect of the pyrolysis temperature and residence time of PKS on the yield of biochar produced and the biochar physio-chemical properties. The results showed that biochar yield decreased as the peak temperature and residence time increased. This finding is consistent with the findings by other researchers. However, those factors do not have distinct influence on biochar's carbon content as found in other study which the peak temperature has the bigger impact instead of residence time. The effect of peak temperature or residence time on grindability; i.e. particle size of biochar after wet ball milled is insignificant. Smaller size of biochar may improve its function as reinforcing filler. As a conclusion, the optimum setup of pyrolysis is needed for a balance production in yield and biochar's properties. It is recommended to produce biochar at higher peak temperature and shorter residence time to increase the total production. Additional analysis e.g. physical testing on the final polymer product can be used to investigate the effect of pyrolysis peak temperature and residence time.
机译:热解是在没有氧的情况下发生生物量的热分解。生物炭(固体),生物油(液体)和沼气(气体)是来自生物质热解的典型产品。这种吸热过程产生了具有高碳含量的生物炭。在热解期间,将材料从环境中加热到峰值温度并保持为限定的停留时间。因此,热解峰温度和停留时间是热解的关键参数。研究这些参数对生物炭特性和热解产物组成的影响很多。然而,与棕榈核壳(PKS)作为生物质的这些参数有限。本研究重点是PKS对生物炭产量和生物炭生理化学性质的热解温和停留时间的影响。结果表明,随着峰值温度和停留时间增加,生物炭产量降低。这一发现与其他研究人员的调查结果一致。然而,这些因素对Biochar的碳含量没有明显影响,如其他研究所发现的峰值温度具有更大的影响而不是停留时间。峰值温度或停留时间对磨削性的影响;即湿球磨后Biochar的粒径微不足道。较小的Biochar尺寸可以改善其功能作为增强填料。作为结论,需要在产量和生物炭的性质中平衡生产来最佳的热解设置。建议在较高峰值温度和较短的停留时间下生产生物炭以增加总产量。额外分析例如最终聚合物产品的物理测试可用于研究热解峰温度和停留时间的影响。

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