首页> 外文会议>International Conference on Nanomaterials for Energy Conversion and Storage Applications >Structural, Compositional and Optical Properties of Spin Coated MoO_3 Thin Film
【24h】

Structural, Compositional and Optical Properties of Spin Coated MoO_3 Thin Film

机译:旋涂MOO_3薄膜的结构,组成和光学性质

获取原文

摘要

The attraction towards the MoO_3 thin film is due to its wide range of application base on its properties. Its application in the field of energy storage and conversion as a cathode material for rechargeable lithium ion battery, hole selective layer in solar cell and in pseudocapacitors makes it more attractive material. Taking in consideration, economical route and tailoring advantage of film formation we have used spin coating method for the synthesis of the film with Ammonium heptamolybdate (NH4)_6Mo_7O_(24) 4H_2O) and distilled water as the precursor and solvent respectively on the glass substrate. The method also provides the large area synthesis of the film which is beneficial for the commercial applications. The film was spin coated at 1600 rpm with 4 % weight per volume ratio. The film so formed was annealed at 300°C for 3 hours. The structural investigation was done by the X-Ray diffraction technique which shows the thin film of polycrystalline type. The average crystallize size is about 50 nm. The composition of the film was studied with the help of EDAX. The optical properties were studied by the photoluminescence and UV Spectroscopy. The results from both the characterization are well matched with each other. Photoluminescence studies show band to band emission observed at 416 nm shown in the fig. 5. From UV spectroscopy, using transmission and absorption spectra we observed the band gap edge around 3 eV. This is in accordance with the photoluminescence result.
机译:朝向Moo_3薄膜的吸引力是由于其各种应用基础。它在储能和转换领域的应用作为可再充电锂离子电池的阴极材料,太阳能电池和假壳体中的孔选择层使其成为更具吸引力的材料。考虑到的经济途径和剪裁的成膜优势我们已经使用旋转涂布方法,用于将膜与氢铵(NH 4)_6mO_7O_(24)4H_2O)和分别在玻璃基板上作为前体和溶剂的蒸馏水来合成。该方法还提供了对商业应用有益的薄膜的大面积合成。将薄膜旋转以1600rpm涂覆,每体积比为4%重量。所形成的薄膜在300℃下退火3小时。结构研究通过显示多晶型薄膜的X射线衍射技术进行。平均结晶尺寸约为50nm。在edax的帮助下研究了薄膜的组成。通过光致发光和UV光谱研究光学性质。两个表征的结果彼此相匹配。光致发光研究表明在图21中所示的416nm处观察到的带发射。 5.从紫外光谱检查,使用传输和吸收光谱,我们观察到3 EV左右的带隙边缘。这符合光致发光结果。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号