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Non-Equilibrium Interactions Between Heavy Oil and Liquid Propane

机译:重油和液体丙烷之间的非平衡相互作用

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In this study,we use a custom-designed visual cell to investigate nonequilibrium interactions between liquid propane(C_(3(1)))and a heavy oil sample(7.2°API)at 55°C.The heavy oil sample is taken from Clearwater Formation located in Western Canadian Sedimentary Basin(WCSB).We inject C_(3(1))into the visual cell containing the heavy oil sample(pressure buildup process)and allow the injected C_(3(1))to interact with the oil sample(soaking process).After the pressure buildup process,we observe three phases in the visual cell: 1)heavy oil(0.67 mol),2)liquid C3(C_(3(1)),0.60 mol),and gaseous C3(C_(3(g)),0.20 mol).We measure visualcell pressure and observe the C3-heavy oil interactions during the pressure buildup and soaking processes. Nonequilibrium interactions occurring at the interfaces of C_(3(1))-heavy oil and C_(3(1))-C_(3(g))are recorded over time. The results show that complete mixing of heavy oil with C_(3(1))occurs in two stages.First,upward extracting flow of hydrocarbon components from bulk heavy oil phase toward C_(3(1))phase form a distinguished layer(L1)during the soaking process.The extracted oil components become denser over time and move down(draining flows)towards the C_(3(1))-heavy oil interface due to gravity.The gradual color change of L1 from colorless to black suggests the mixing of hydrocarbon components from heavy oil.After L1 becomes homogenous,a second layer(L2)is formed at the upper part of the bulk C_(3(1))phase(above L1). Extracting and draining flows becomes active once again,leading to mixing of oil components from L1 into L2.At equilibrium condition,heavy oil and C_(3(1))are completely mixed and form a single homogenous phase.
机译:在这项研究中,我们使用定制设计的视觉电池来研究液体丙烷(C_(3)))和55℃下重油样品(7.2°API)之间的非预纤维相互作用。重质油样品取出位于加拿大西部沉积盆(WCSB)的透明层组。将C_(3(1))注入含有重油样品(压力累积过程)的视觉池中,并允许注入的C_(3(1))与之相互作用油样(浸泡过程)。压力累积过程中,观察视觉池中的三个阶段:1)重油(0.67mol),2)液体C3(C_(3(1)),0.60mol)和气体C3(C_(3(g)),0.20摩尔).We测量VisualCell压力,并在压力累积和浸泡过程中观察C3重油相互作用。在C_(3(1)) - 重油和C_(3(1)) - C_(3(g))的界面处发生不足相互作用。随时间记录。结果表明,用C_(3(1))完全混合用C_(3(1))发生在两个阶段中。首先,向上提取烃组分的烃组分从体重重油相朝向C_(3(1))相形成占聚层(L1 )在浸泡过程中,提取的油组分随着时间的推移变得更浓,并向C_(3(1)) - 由于重力而向下移动(排出流量) - 从无色到黑色的L1的逐渐变化表明将烃组分从重油中混合。在L1中,L1变为均匀,第二层(L2)形成在散装C_(3(1))相的上部(3(1))相(在L1上方)。提取和排出流动再次变得活跃,导致从L1进入L2的油组分混合。均衡条件,重油和C_(3(1))完全混合并形成单一均匀相。

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