Cr(VI) Removal on Visible Light Active TiO_2 Nanotube Arrays

摘要

Self-organized TiO_2 nanotube (TNT) arrays were fabricated by anodic oxidation of titanium foil in three different fluoride electrolytes: ethylene glycol (EG), glycerol, and sodium sulfate (Na2SO_4) at different voltage and anodization time. In these electrolytes, the TNTs were produced in~ 2 μm long, but at the different diameter. The size of inner diameter can be arranged from the largest to the smallest value in the order of glycerol> EG> Na2SO_4. Crystallization of the TNTs by annealing was led to the formation of anatase-TiO_2. The sample can be activated under natural sunlight for reduction of hexavalent chromium, Cr(VI) into trivalent chromium, Cr(III). The reduction was thought to occur via synergistic reactions between adsorption and photoreduction. The result demonstrates 100 % of Cr(VI) removal efficiency over the TNTs grown in EG after 120 min. Whereas, only 48 % and 45 % of Cr(VI) can be removed over the TNTs fabricated in glycerol and Na2SO_4, respectively. High photocatalytic activity of the TNTs-EG can be attributed to high crystallinity of anatase phase, enhanced Cr(VI) adsorption, and less electron-hole recombination due to smoother tube walls.