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An Experimental Study of Emulsion Flow in Alkaline Solvent Coinjection with Steam for Heavy-Oil/Bitumen Recovery

机译:碱性溶剂投入蒸馏物的乳液流动对重油/沥青回收的实验研究

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Water is the dominant component in steam injection processes, such as steam-assisted gravity drainage (SAGD). The central hypothesis in this research is that in-situ oil transport can be enhanced by generating oil-in-water emulsion, where the water-continuous phase acts as an effective oil carrier. As part of the research project, this paper presents an experimental study of how oil-in-water emulsion can improve oil transport in porous media at elevated temperatures from 373 K to 443 K. Diethyl amine (DEA) was selected as the organic alkali to form oil-in-water emulsions with Athabasca bitumen and NaCl brine at 1000 ppm salinity and 0.5 wt% alkali concentration. This composition had been confirmed to be optimal in terms of oil solubility in the water-external emulsion phase at a wide range of temperatures. Then, flow experiments with a glass-beads pack were conducted to measure effective viscosities for emulsion samples at shear rates from 5 to 29 sec?1. Results show that the oil-in-water emulsions were more than 18 times less viscous than the original bitumen at 373 and 403 K. At an estimated shear rate of 5 sec?1, for example, the emulsion viscosity was 12 cp at 373 K, at which the bitumen viscosity was 273 cp. The efficiency of in-situ bitumen transport was evaluated by calculating bitumen molar flow rate under gravity drainage with the new experimental data. Results show that oil-in-water emulsion can enhance in-situ molar flow of bitumen by a factor of 64 at 403 K and 95 at 373 K, in comparison with the gravity drainage of oil-water two phases in conventional SAGD. This is mainly because the mobility of the bitumen-containing phase is enhanced by the reduced viscosity and increased effective permeability. A marked difference between alkaline solvents and conventional hydrocarbon solvents is that only a small amount of alkaline solvent enables to enhance in-situ transport of bitumen.
机译:水是蒸汽喷射过程中的主要成分,例如蒸汽辅助重力排水(SAGD)。本研究中的中央假设是通过产生水包油乳液可以提高原位油,其中水连续相用作有效的油载体。作为研究项目的一部分,本文提出了一种实验研究,对水包油乳液可以在373k至443k的升高温度下改善多孔介质中的油运输的实验研究。选择亚乙胺(DEA)作为有机碱用Athabasca沥青和NaCl盐水形成油包水乳液,盐度为0.5wt%碱浓度。在各种温度下,已确认该组合物在水外乳液相中的油溶性方面是最佳的。然后,进行具有玻璃珠包的流动实验,以测量剪切速率的乳液样品的有效粘度,从5至29秒α1。结果表明,水质乳液比在373和403k的原始沥青中粘稠的粘稠含量越来越小。在估计5秒α1的估计剪切速率下,例如,乳液粘度为12cc为373k ,沥青粘度为273cp。通过使用新的实验数据计算重力引流沥青摩尔流速来评估原位沥青传输的效率。结果表明,与常规SAGD的油水两相的重力引流,水包油乳液可以增强沥青的原位摩尔流量为64,在373 k下以403k和95倍。这主要是因为通过降低的粘度和增加的有效渗透性来增强含沥青相的迁移性。碱性溶剂和常规烃溶剂之间的显着差异是,只有少量的碱性溶剂能够增强沥青的原位运输。

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