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Simultaneous Reduction and Covalent Combining of Tetraethylenepentamine on Graphene Oxide

机译:二亚乙基二胺在氧化烯酮上同时减少和共价组合

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[Objective] To prepare tetraethylenepentamine functionalized reduced graphene oxide (TEPA-Gn) by a one-step process. [Method] Tetraethylenepentamine (TEPA) was grafted with graphene oxide (GO) under mild condition of 70°C and in the presence of sodium hydroxide which acted as a catalyzer. [Results] The structural analysis of TEPA-Gn by FTIR and XPS showed that tetraethylenepentamine was attached to the six-membered ring of graphene by forming a covalent bond with an epoxy group in GO. Raman spectrum showed that the disorder of TEPA-Gn increased. [Conclusion]The tetraethylenepentamine was both a linker agent and a reducing agent in the reaction of preparing TEPA-Gn.
机译:[目的]通过一步法制备四亚乙烯二胺官能化的石墨烯氧化物(TEPA-GN)。 [方法]在70℃的温和条件下用石墨烯(GO)和用作催化剂的氢氧化钠存在,用石墨烯丁胺(GO)接枝四亚乙基二胺(TEPA)。 [结果] FTIR和XPS对TEPA-GN的结构分析表明,通过与环氧基团的共价键与环氧树脂的共价键连接到六元环烯上。拉曼光谱表明,TEPA-GN的病症增加。 [结论]在制备TEPA-GN的反应中,四亚乙基二胺在反应中是接头剂和还原剂。

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