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Photocatalytic Performance of Fe_3O_4/TiO_2/Ag Nanocomposites for Photocatalytic Activity Under Visible Light Irradiation

机译:可见光照射下光催化活性Fe_3O_4 / TiO_2 / Ag纳米复合材料的光催化性能

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In this work, Fe_3O_4/TiO_2 nanocomposites with additional silver metal were used as a catalyst for methylene blue removal in aqueous solution. Fe_3O_4/TiO_2/Ag Nanocomposites with various weight percentages of Ag (5 wt.%, 15 wt.% and 25 wt.%) were successfully synthesized using the sol-gel method. All samples were characterized using X-Ray Diffraction (XRD), and UV-vis spectrometry was used to determine the crystalline phase and optic properties of the sample nanocomposites. The catalytic activity of the samples was carried out using photocatalytic experiment. The result showed that addition of silver could enhance the catalytic performance significantly. The photocatalyst Fe_3O_4/TiO_2/Ag 25 wt.% showed highest photocatalytic activity. The holes are the main active species in the photocatalytic activity mechanism is indicated in experiment. Lastly, nanocomposites have a good stability after being reused for four times of cycling process.
机译:在这项工作中,用额外的银金属Fe_3O_4 / TiO_2纳米复合材料用作水溶液中亚甲基蓝色去除的催化剂。使用溶胶 - 凝胶法成功地合成Fe_3O_4 / TiO_2 / Ag纳米复合材料,其具有各种重量百分比的Ag(5重量%,15重量%和25重量%)。使用X射线衍射(XRD)表征所有样品,使用UV-Vis光谱法测定样品纳米复合材料的结晶相和光学性质。使用光催化实验进行样品的催化活性。结果表明,添加银可以显着提高催化性能。光催化剂Fe_3O_4 / TiO_2 / Ag 25重量%显示最高的光催化活性。孔是光催化活性机制中的主要活性物质在实验中表明。最后,纳米复合材料在重复使用4次循环过程后具有良好的稳定性。

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