Effect of epoxidised soybean oil loading as plasticiser on physical, mechanical and thermal properties of polyvinylchloride

摘要

The aim of this paper is to study the effect of epoxidised soybean oil (ESO) as an alternative plasticizer on physical, mechanical and thermal properties of plasticised polyvinyl chloride (PPVC). Samples were prepared using 10, 20, 30 and 40% by weight percent of ESO. The samples were characterized for density, water absorption, tensile, hardness and thermal properties. The addition of ESO as plasticizer in PVC had caused significant effect on the physical and mechanical properties of PPVC. Increasing of ESO loading had resulted in decreased density, tensile strength, tensile modulus but increased in elongation at break and shore hardness. From water absorption study, it was observed that the all the samples reached the plateau absorption at days 8 to 10 with absorption percentages of between 1.8 to 2%. In general the crystallinity of PPVC maintained between 10 to 13% with increase in ESO loading while the melting point ( T_m) is slightly decreased about 3 to 6°C. In this study, ESO which acts as plasticiser were found to result in lower glass transition temperature (T_g). The enhancements of super cooling with higher ESO loading were found to increase the crystallization temperature, promoting crystallisation and act as nucleating agent.