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SURFACE TENSION MEASUREMENT OF LOW GWP REFRIGERANTS

机译:低GWP制冷剂的表面张力测量

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HFOs (hydro-fluoro-olefins) are very recently under consideration as a potential candidate of R410A alternatives with GWP of 2800 that is most widely used in air-conditioning and refrigeration systems. The capillary constant and surface tension of R32, R1234ze(E), and their binary mixture R32/R1234ze(E) are measured in the temperature range from 274 K to 342 K by the differential capillary rise method. The propagated uncertainty in the surface tension is estimated within 0.3 mN m~(-1). The experimentally quantified surface tensions of the components R32 and R1234ze(E) well agree with the calculated value by REFPROP 9.1. The measured surface tension of R32/R1234ze(E) at charged compositions 51/49 mass% and 43/57 mass% reasonably agree with the correlation for R32/R1234ze(E) (50/50 mass%) proposed by Tanaka and Higashi [1]. The surface tension data presented in this study and avairable in literatures (Tanaka and Higashi [1]; Cui et al. [2]) appear to vary almost linearly against mole fraction at a fixed reduced temperature.
机译:最近考虑了HFOS(水氟烯烃)作为R410A替代品的潜在候选者,GWP为2800,最广泛地用于空调和制冷系统。 R32,R1234(E)的毛细管常数和表面张力和其二元混合物R32 / R1234ZE(E)通过差分毛细管升高方法测量在274k至342k的温度范围内。表面张力中的传播不确定性估计在0.3mN m〜(-1)范围内。通过REFPROP 9.1的分量R32和R1234ze(E)的实验定量表面张力与计算值相同。 R32 / R1234ze(E)的测量表面张力在带电组合物中的51/49质量%和43/57质量%合理地与Tanaka和Higashi提出的R32 / R1234ze(E)(50/50质量%)的相关性相提并1]。本研究中呈现的表面张力数据和在文献中的纵向(Tanaka和Higashi [1]; Cui等人。[2])似乎在固定的降低的温度下对摩尔分数几乎线性地线性变化。

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