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Laboratory study: The development of a sodium lignosulfonate (SLS) surfactant formulation for light oil reservoir to improve oil recovery

机译:实验室研究:轻油储层硫代磺酸钠(SLS)表面活性剂配方的开发,提高油回收

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Sodium lignosulfonate is an anionic surfactant that has good potential for enhanced oil recovery (EOR). Surfactants based on sodium lignosulfonate (SLS) are selected because they can be synthesized from renewable materials, available raw materials, relatively cheaper than other surfactants, and are environmentally friendly. Previous studies on SLS for the EOR show SLS performance not yet optimum, so it needs to be formulated to improve its performance. The formulations applied in this study were the addition of sodium oleate as cosurfactant and ethylene glycol butyl ether (EGBE) as dispersants, with a ratio of 80% of SLS surfactants: 16% sodium oleate: 4% EGBE. Tests conducted in this study included the SLS surfactant compatibility test in the laboratory scale and continued to the coreflooding test. The compatibility test consisted of aqueous stability test, phase behavior test, and interfacial tension test (IFT) with three test concentrations. All testing was done for light oil reservoir. The SLS surfactant solution before formulation showed the two phases in aqueous stability test and high IFT in 10~(-1)mN/m while after formulation the IFT reached 10~(-3)mN/m. The phase behavior before and after formulation showed the same performance, in low concentration had lower phase and in high concentration had middle phase. The incremental recovery from coreflood test using 0.5 % and 1 % concentration of SLS formulation were 34.09 % and 37.5 % respectively. The results showed that SLS surfactant can be good candidate for chemical EOR.
机译:木质素磺酸钠是阴离子表面活性剂,具有良好的增强的溢油(EOR)潜力。选择基于木质素磺酸钠(SLS)的表面活性剂,因为它们可以由可再生材料合成,可用的原料,比其他表面活性剂相对便宜,并且是环保的。以前关于EOR的SLS的研究表明SLS性能尚未最佳,因此需要配制它以提高其性能。本研究中施用的制剂是将含钠油酸钠和乙二醇丁醚(EGBE)作为分散剂的加入,其比例为80%的SLS表面活性剂:16%钠油酸钠:4%EGBE。本研究中进行的测试包括在实验室规模中的SLS表面活性剂相容性测试,并继续持续到核心开采试验。相容性测试由稳定性试验,相行为试验和具有三种测试浓度的界面张力试验(IFT)组成。所有测试都是为轻油储层完成的。在制剂之前,SLS表面活性剂溶液显示在稳定性试验中的两个相,在配制后10〜(-1)Mn / m中的高IFT在配制后,IFT达到10〜(3)Mn / m。制剂前后的相行为显示出相同的性能,低浓度具有较低的阶段,高浓度具有中间阶段。使用0.5%和1%浓度的SLS制剂的CoreFlood测试的增量回收分别为34.09%和37.5%。结果表明,SLS表面活性剂可以是化学EOR的良好候选者。

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