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Optimization of palmitic acid extraction from palm oil with betaine-based natural deep eutectic solvent using response surface methodology

机译:用响应面法测定棕榈油棕榈油棕榈酸提取的优化

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Deacidification is one of many steps in the palm oil refining process which aims to separate free fatty acids from the oil. The deacidification process was using green solvent, known as deep eutectic solvent (DES), that consisted of betaine anhydrous and hydrogen bonding donor of 1,2-propanediol (DES-1) and 1,4-butanediol (DES-2) at a molar ratio of 1:5 and 1:4, respectively. In this study, the process condition was optimized using response surface methodology (RSM) through central composite design to predict the maximum palmitic acid content in DES extract. The independent variables were extraction temperature (40, 60, 80°C) and mass ratio of DES to oil (1:2, 1:1, 2:1). The p-values obtained from the ANOVA of the extraction yield data indicates that the dependence of the extraction yield of palmitic acid on DES to palm oil mass ratio and extraction temperature were linear and quadratic, respectively. The result shows that betaine anhydrous and 1,4-butanediol DES in molar ratio of 1:4 could extract palmitic acid up to 49.9% at temperatureof 42.8°C and DES to oil mass ratio of 2:1.
机译:Deacidification是棕榈油精炼过程中的众多步骤之一,旨在将来自油的游离酸分离。使用绿色溶剂,称为深度共晶溶剂(DES),其由1,2-丙二醇(DES-1)和1,4-丁二醇(DES-2)的甜菜碱无水和氢键供体组成。摩尔比分别为1:5和1:4。在该研究中,通过中央复合设计使用响应表面方法(RSM)优化过程条件,以预测DES提取物中的最大棕榈酸含量。独立变量是提取温度(40,60,80℃)和DES的质量比(1:2,1:1,2:1)。从提取产率数据的ANOVA获得的p值表明,棕榈酸的提取产率对棕榈油质量比和提取温度的依赖性分别是线性和二次的。结果表明,β-无水和1,4-丁二醇DES的摩尔比为1:4可以在42.8℃和DES的温度下提取棕榈酸,高达49.9%,为2:1的油质量比。

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