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Comparing nitrate production through CGDE (contact glow discharge electrolysis) using Na_2SO_4 solution and K_2SO_4 solution

机译:使用Na_2SO_4溶液和K_2SO_4溶液将硝酸盐产生通过CGDE(接触辉光放电电解)

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Fertilizer is the most important thing in agriculture to nourish the plant to produce high quality harvest. The most important element in fertilizer is nitrogen which comes from the air. The form of nitrogen in fertilizer are ammonia with fertilization efficiency 40% and nitrate with fertilization efficiency 60%. The recent industrial fertilizer production process, ammonia synthesis which called Haber-Bosch process, still not environmentally friendly and also consume high energy. Environmentally friendly and lower energy process is needed to produce fertilizer. Some study related to nitrogen fixation to produce fertilizer has been made including Contact Glow Discharge Electrolysis (CDGE). Contact Glow Discharge Electrolysis (CGDE) is an effective technology to fix nitrogen from the air into the solutions because of its ability to produce reactive species such as hydroxyl radicals and electrons to break the N_2 bond and transfer it into the solution. This study is comparing CDGE in Na_2SO_4 solution and K_2SO_4 solution and will be implemented in batch reactor, in 600 and 800 watts, in 0.02 M concentration, anode depth 1.5 and 3.5 cm, with air injection flow rate 0.2 liter per minute as the source of nitrogen and 1,5 liter of solution is used. Plasma in K_2SO_4 had better nitrate production in both conditions used.
机译:肥料是农业最重要的是滋养植物以产生高质量的收获。肥料中最重要的元素是来自空气的氮。施肥中氮的形式是氨的施肥效率40%和硝酸盐,受精效率为60%。最近的工业肥料生产过程,氨合成称为Haber-Bosch工艺,仍然没有环境友好,也消耗了高能量。需要环保和较低的能量过程来生产肥料。已经进行了与氮固定有关的研究,包括产生肥料,包括接触焕发放电电解(CDGE)。接触辉光放电电解(CGDE)是一种有效的技术,可以将氮气从空气中固定到溶液中,因为它能够产生反应性物质,例如羟基自由基和电子以破坏N_2键并将其转移到溶液中。该研究正在比较Na_2SO_4溶液中的CDGE和K_2SO_4溶液,并将在批量反应器中,600和800瓦,以0.02M浓度,阳极深度1.5厘米,空气喷射流量0.2升/分钟作为批量来实现使用氮气和1.5升溶液。 K_2SO_4中的血浆在两种条件下具有更好的硝酸盐产生。

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