Fabrication and Characterization of Low Thermal Expansion Cordierite/Spodumene/Mullite Composite Ceramic for Cookware

摘要

Ceramic cookware can be taken a direct flame or stove top for the duration without damage. The selected materials must have low thermal expansion coefficient, high strength, low water absorption and high thermal shock resistance, reasonable in cost and easy to be produced. Cordierite and spodumene composite has been interested for ceramic cookwar6 due to their fitted properties. In previous work, study in the cordierite-spodumene composite with low thermal expansion coefficient of 2.60 x 10~(-6)/°C when sintered at 1250 °C with a ratio of spodumene 60 wt% and cordierite 40 wt% can withstand the pot shape samples. However, the sample showed relatively high water absorption and low strength which was not appropriate for using in this application. In this research, mullite is added in the formula to improve strength and densification of ceramic composites. Spodumene, ball clay, calcined talc and calcined alumina are used as starting raw materials and formed by slip casting. All samples are sintered in a temperature range from 1250-1275 °C in an electric furnace. Water absorption and bulk density were tested by Archimedes method, modulus of rupture was tested by the three-point bending method, microstructure were investigated by SEM and the coefficient of thermal expansion was measured by dilatometer. It was found that the mullite phase was investigated when adding mullite more than 30 wt%in cordierite-spodumene composite.