Synthetic Study towards (+)-Clavosolide A: Synthesis of the Intermediate of (R)-methyl 5-hydroxy-3-oxoheptanoate

机译：（+） - 石棉苷的合成研究A：（R）中间体的合成 - 甲基5-羟基-3-氧己酸酯

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摘要

The important intermediate, (R)-methyl 5-hydroxy-3-oxoheptanoate, of study towards to total synthesis of (+)- Clavosolide A (1) was described, which was commenced from commercially available D-phenylalanine.

机译：描述了重要的中间体，（R） - 羟基-3-氧己酰胺，其研究朝向总合成（+） - 克拉沃醇醚A（1），其从市售的D-苯丙氨酸开始。

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《International Conference on Machinery, Materials Engineering, Chemical Engineering and Biotechnology》|2016年|506-1007p|共4页
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作者
Xiao Leng; Tianxiang Xu; Shuangping Huang; Xiaoji Wang;
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中图分类 TB3-53;
关键词
(R)-methyl 5-hydroxy-3-oxoheptanoate; (+)-Clavosolide A; Synthesis;

机译：（r） - 甲基5-羟基-3-氧庚酸盐;（+） - 克拉莫酚A;合成;

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专利

1. Studies directed towards the total synthesis of clavosolides: synthesis of an isomer of clavosolide A [J] . Chakraborty TK, Reddy VR Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2006,第13期

机译：直接合成clavosolides的研究：clavosolide A异构体的合成
2. Synthetic studies toward the preparation of (4R,5R)-(-)-3-[(benzyloxy)methyl]-4,5-O-isopropylidene-cyclopenten-2-one: an important synthetic intermediate for carbanucleosides [J] . Elhalem E, Comin MJ, Leitofuter J, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2005,第2期

机译：合成制备（4R，5R）-（-）-3-[（苄氧基）甲基] -4,5-O-异亚丙基-环戊烯-2-酮的合成研究：碳核苷的重要合成中间体
3. Synthetic Approaches towards ?-Furylparaconic Acid Methyl Ester ? An Important Intermediate for the Synthesis of Pseudopterogorgia Diterpenoids. [J] . E. KADIVAR, Kh. RAHIMI, M. A. SHAHZAMANIAN Research Journal of Pharmaceutical, Biological and Chemical Sciences . 2014,第6期

机译：合成α-呋喃基对conconic酸甲酯的方法假单胞菌二萜类化合物合成的重要中间体。
4. Synthetic Study towards (+)-Clavosolide A: Synthesis of the Intermediate of (R)-methyl 5-hydroxy-3-oxoheptanoate [C] . Xiao Leng, Tianxiang Xu, Shuangping Huang, International Conference on Machinery, Materials Engineering, Chemical Engineering and Biotechnology . 2016

机译：（+） - 石棉苷的合成研究A：（R）中间体的合成 - 甲基5-羟基-3-氧己酸酯
5. I. New Methodologies and Catalysts for the Diels—Alder Reaction II. Computational and Synthetic Studies Toward the Total Synthesis of (–)-Stenine III. Synthetic Studies Toward the Total Syntheses of N-Methyl Welwitindolinone C isothiocyanate and N-Methyl Welwitindolinone B isothiocyanate [D] . Cleary, Leah 2013

机译：I. Diels-Alder反应的新方法和催化剂II。对（-）-Stenine III完全合成的计算和综合研究。 N-甲基韦尔吲哚啉酮C异硫氰酸酯的总合成的合成研究
6. Chemical and enzymic studies on the characterization of intermediates during the removal of the 14alpha-methyl group in cholesterol biosynthesis. The use of 32-functionalized lanostane derivatives. [O] . M Akhtar, K Alexander, R B Boar, 1978

机译：在胆固醇生物合成中去除14α-甲基过程中中间体的表征的化学和酶学研究。使用32-官能化羊毛脂衍生物。
7. Synthetic Study towards (+)-Clavosolide A: Synthesis of the Intermediate of (R)-methyl 5-hydroxy-3-oxoheptanoate [O] . Xiao Leng, TianXiang Xu, Shuangping Huang, 2016

机译：（+） - 石棉苷的合成研究A：（R）中间体的合成 - 甲基5-羟基-3-氧己酸酯
8. Secondary Free Radial Intermediates in the Synthesis of 2-Methyl-6-Nitroindazole [R] . Boyer, J. H., Pace, M. D., Pagoria, P., 1986

机译：二甲基自由基中间体合成2-甲基-6-硝基吲唑

Synthetic Study towards (+)-Clavosolide A: Synthesis of the Intermediate of (R)-methyl 5-hydroxy-3-oxoheptanoate

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