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Preparation of Y(OH)_3:Eu~(3+) and Y_2O_3:Eu~(3+) with Nanotube Morphology by a Facile Hydrothemal Method

机译:Y(OH)_3:Eu〜(3+)和Y_2O_3:Eu〜(3+)通过容易水疗法的纳米管形态

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In this work, Y(OH)_3:Eu~(3+) nanotubes with 2-3 μm in length and 50-300 nm in diameter have been successfully synthesized on a large scale by hydrothermal treatment of the corresponding oxides in pure water. In addition, Y_2O_3:Eu~(3+) nanotubes could be obtained by calcination of Y(OH)_3:Eu~(3+) nanotubes in air at 450°C. X-ray powder diffraction (XRD), Field-emission scanning electron microscopic (FE-SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED), energy-dispersive X-ray spectra (EDS) and the photoluminescence spectra (PL) have been employed to characterize these nanotube materials. The growth mechanism as-prepared nanotubes could be explained well by the highly anisotropic crystal structure of rare earth hydroxides. Advantages of this method were simple, highly reproducible, inexpensive, and widely applicable for the large-scale industrial production.
机译:在这项工作中,Y(OH)_3:Eu〜(3+)长度为2-3μm的纳米管,直径为50-300nm,通过纯水中的相应氧化物的水热处理成功地合成大规模。另外,Y_2O_3:Eu〜(3+)纳米管可以通过在450℃下的空气中的Y(OH)_3:Eu〜(3+)纳米管煅烧获得。 X射线粉末衍射(XRD),现场 - 发射扫描电子显微镜(Fe-SEM),透射电子显微镜(TEM),高分辨率透射电子显微镜(HRTEM),选定区域电子衍射(SAED),能量分散X - 已经采用-REAR谱(EDS)和光致发光光谱(PL)来表征这些纳米管材料。可以通过稀土氢氧化物的高各向异性晶体结构来解释为制备的纳米管的生长机制。该方法的优点是简单,高度可重复,廉价,广泛适用于大型工业生产。

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