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Matching plasmon resonances to the C=C and C-H bonds in estradiol

机译:将等离子体共振与雌二醇中的C = C和C-H键相匹配

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We tune nanoantennas to resonate within mid-infrared wavelengths to match the vibrational resonances of C=C and C- H of the hormone estradiol. Modelling and fabrication of the nanoantennas produce plasmon resonances between 2 um to 7 um. The hormone estradiol was dissolved in ethanol and evaporated, leaving thickness of a few hundreds of nanometres on top of gold asymmetric split H-like shaped on a fused silica substrate. The reflectance was measured and a red-shift is recorded from the resonators plasmonic peaks. Fourier transform infrared spectroscopy is use to observe enhanced spectra of the stretching modes for the analyte which belongs to alkenyl biochemical group.
机译:我们调谐纳米环绕以在中红外波长内谐振以匹配C = C和激素雌二醇的C-H的振动共振。纳米环的建模和制造在2μm至7μm之间产生等离子体共振。将激素雌二醇溶解在乙醇中并蒸发,在熔融二氧化硅衬底上的金不对称分裂H样上留下几百纳米的厚度。测量反射率并且从谐振器等离子体峰记录了红转。傅里叶变换红外光谱用于观察属于链烯基生物化学基团的分析物的拉伸模式的增强光谱。

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