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Impact of Pb Content on the Physical Parameters of Se-Te-Pb System

机译:PB含量对SE-TE-PB系统物理参数的影响

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In the present study, we have investigated the impact of Pb content on the physical parameters in Se-Te-Pb system via average coordination number, constraints, the fraction of floppy modes, cross-linking density, lone pairs electrons, heat of atomization, mean bond energy, cohesive energy and electronegativity. The bulk samples have been prepared by using melt quenching technique. X-ray diffraction pattern of various samples indicates the amorphous nature of investigated glassy alloys. It is observed that average coordination number, average number of constraints and cross-linking density increase with Pb content. However, lone-pair electrons, floppy modes, average heat of atomization, cohesive energy and mean bond energy are found to decrease with Pb atomic percentage.
机译:在本研究中,我们已经通过平均配位数,约束,软盘模式,交联密度,孤复对电子,雾化热,雾化热,雾化热,雾化热,雾化,雾化热,雾化的分数,研究了PB含量对SE-TE-PB系统的物理参数的影响。平均粘合能量,粘性能量和电负性。通过使用熔融淬火技术制备散装样品。各种样品的X射线衍射图案表明了研究的玻璃合金的无定形性质。观察到平均配位数,平均约束数和交联密度随PB含量的增加。然而,发现孤立电子,软盘模式,雾化的平均热量,粘性能量和平均键能量以PB原子百分比降低。

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