Mineralogical distribution of base metal sulfides in processing products of black shale-hosted Kupferschiefer-type ore

摘要

The extraction of copper from black shales associated with fine-grained and complex base metal ore mineralization traditionally using pyrometallurgy becomes increasingly uneconomic. Since energy consumption is one of the most significant cost factors in the mineral processing, energy-saving alternative processing methods are to be considered to improve the metal recovery route economically and environmentally. In this study, a milled, organic carbon-rich black shale ore from the Sangerhausen mining district in central Germany has been pre-treated by ethanol prior to the froth flotation tests to gain a copper concentrate marked by an increased copper content and more efficient copper recovery. The flotation product (13.9% Cu) has been utilized for bioleaching bioreactor batch tests to recover copper and associated trace metals biohydrometallurgically. SEM-based automated particle analyses on the comminuted black shale ore, flotation product as well as tailings, bioleaching residues and abiotic leaching residues, respectively, were used to trace the recovery performance by the distribution of sulfides and gangue minerals. The black shale ore is characterized by increased contents of bornite (2.7 wt.%) and chalcopyrite (1.5 wt.%) associated with a high grade of pyrite (6.2 wt.%). Considerable enrichments were achieved in the flotation product for bornite (20.7 wt.%) and chalcopyrite (10.3 wt.%) as well as for galena and sphalerite, while pyrite was successfully depressed in the tailings. Compared to abiotic chemical leaching, the bioleaching test of the bornite- and chalcopyrite-rich copper concentrate was particular efficient in the recovery of bornite and chalcocite. However, chalcopyrite was leached insufficiently in both, abiotic and microbial leaching tests, and presents a common component in the residues.