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A Model for Extending the Heptanes plus Fraction for Trinidad Gas Condensates

机译:用于将庚烷延伸的模型加上特立尼达气凝块的馏分

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An accurate description of pseudo-component compositions is required for Equation of State predictions for gas condensate systems. Very often these extended experimental data are unavailable and must be generated using mathematical models, of which the exponential and the three-parameter gamma distri- bution functions are the two most widely used. The development of these two techniques was based on the assumption of a continuous molar relationship for pseudo-components. However, experimental compositional data for gas condensate systems show discontinuities in this relationship at SCN8 and SCN13. The above models when applied to extend the C_(7+) fraction for Trinidad gas condensates, under predict the SCN8 mole percent and over predict the SCN12 mole percent due to the aforementioned disconti- nuities. The Average Absolute Deviation between the predicted and experimental SCN8 and SCN12 data were both greater than 25 percent. The two coefficient method described by Ahmed et al., when applied to extend the C_(7+) fraction, reduced the discontinuity at SCN8 to less than 12 percent. However the SCN12 group still had a deviation greater than 18 percent. These results show that existing models were not designed to take care of these discontinuities and should be used with caution when extending experi- mental data beyond SCN7. The Model described in this study resolves these discontinuities in the molar relationships at both SCN8 and SCN12 with an Average Absolute Deviation between the predicted and experimental compo- sitions of less than 10 percent. This model can quite easily be included in Equation of State packages for a more accurate description of compositions for Trinidad gas condensates for performing compositional simulation studies. A partial analysis beyond the C_(7+) fraction is not required with this new model.
机译:对于气体冷凝物系统的状态预测等式,需要准确描述伪组分组合物。通常,这些扩展的实验数据通常不可用,必须使用数学模型生成,其中指数和三参数伽马分散函数是最广泛使用的两个。这两种技术的发展是基于对伪组分的连续摩尔关系的假设。然而,用于气体凝结系统的实验组成数据显示SCN8和SCN13在这种关系中的不连续性。上述型号施加时延伸到三角达气体缩合物的C_(7+)馏分,预测ScN8摩尔百分比和过度预测SCN12摩尔百分比由于上述的不置核酸。预测和实验SCN8和SCN12数据之间的平均绝对偏差均大于25%。 Ahmed等人描述的两个系数方法,当施加延伸C_(7 +)分数时,将SCN8的不连续性降低至小于12%。然而,SCN12组仍偏差超过18%。这些结果表明,现有模型并非设计用于处理这些不连续性,并且应在超越SCN7超出SCN7之外的实验数据时小心使用。本研究中描述的模型解决了SCN8和SCN12的摩尔关系中的这些不连续性,预测和实验组合之间的平均绝对偏差小于10%。该模型可以很容易地包括在状态封装的方程中,以更准确地描述用于进行组合模拟研究的三达达气体缩合物的组合物。这种新模型不需要超出C_(7+)分数的部分分析。

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