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PYROLYSIS OF EASTERN REDCEDAR IN A FLUIDIZED-BED AND A DROP-TUBE REACTORS FOR BIO-OIL PRODUCTION

机译:在流化床和生物油生产中的东部红柱热解,用于生物油生产

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Eastern red cedar, a middle sized conifer with a pyramidal shape, is native to the Eastern United States. Due to strong resilience towards various soil and climate conditions, eastern red cedar has become an invading species on the prairies, which has aggressively spread to the Midwest states. For example, in Oklahoma, more than seven million acre land is covered by eastern red cedar1. The invasion of eastern red cedar leads to severe impacts on the local ecosystems, such as loss of native plants and birds, reduction of forage production and livestock handling, impacts on soil hydraulic properties. Last but not least, eastern red cedar contains chemical compounds that burn rapidly which makes it a susceptible to forest fire. Currently the best control available to prevent eastern cedar from encroaching the prairies is cutting the trees and then burning them. Up till now, application of eastern red cedar is mainly focused on the extraction of cedarwood oil, which is an important feedstock for the production of fragrances, essential oils, insecticides and antifungals . Several approaches such as steam distillation, solvent extraction and super critical fluid extraction have been used to recover cedar wood oil. The oil yield depends mainly on the techniques used and the properties of the wood. However, on average, the oil yield from eastern red cedar reported in the literature only ranges from 1 to 4.6% ! Such low production of oil will definitely become a challenge for the efficient utilization of eastern red cedar. Therefore, alternative techniques and processes that can utilize most of the biomass with the lowest cost should be investigated. Fast pyrolysis of eastern red cedar for bio-oil production has potential to utilize most of the biomass. The pyrolysis-derived bio-oil could be either upgraded to transporting fuel in biorefineries or used for chemical extraction. Compared to fast pyrolysis, steam distillation requires much longer residence time (more than 20 hrs), solvent extraction undergoes in high pressure condition (1500-10000 psi) '. Moreover, cedar wood oil recovery methods also use more complex reactor systems. Thus, fast pyrolysis can provide a cost-effective route to utilize the eastern red cedar. The objective of this paper was to investigate the impacts of pyrolysis operation conditions including pyrolysis temperature, gas flow rate and particle size on the bio-oil yield, bio-oil properties and carbon conversion efficiency using eastern red cedar as the biomass feedstock. This study was designed to validate the fast pyrolysis as an efficient method to utilize eastern red cedar.
机译:东方红杉,一个中型的针叶树,金字塔形状,原产于美国东部。由于对各种土壤和气候条件,较强的抗跌性,东方红杉树已经成为了草原,已积极蔓延到中西部各州的入侵物种。例如,在俄克拉何马州,七百多万每亩土地由东红cedar1覆盖。东方红雪松导致对当地生态系统造成严重影响,如原生植物和鸟类,饲料生产减少和牲畜处理的,对土壤水力性质影响的损失的入侵。最后但并非最不重要的,东方红雪松含有迅速燃烧,这使得它容易受到森林火灾的化合物。目前市面上最好的控制,以防止东部雪松侵占草原被切割树木,然后焚烧他们。截至目前,东方红杉树的应用主要集中在雪松油的提取,这是用于生产香料,精油,杀虫剂和杀真菌剂的重要原料。有几种方法,例如蒸汽蒸馏,溶剂萃取和超临界流体萃取已经被用于回收雪松木油。油的产量主要取决于所使用的技术和木材的特性。然而,平均而言,从东部红雪松油产量文献仅报道的范围从1到4.6%!如此低的产油肯定会成为东方红杉的有效利用是一个挑战。因此,可替代的技术和方法,其可以利用大多数生物质的具有最低成本应进行调查。生物油生产的东红杉的快速热解有潜力利用大部分的生物质。热解衍生的生物油可以要么升级到运输燃料中生物炼制或用于化学萃取。相比快速热解,蒸汽蒸馏需要更长的停留时间(超过20个小时)在高压条件(1500-10000 psi)的,溶剂萃取经历”。此外,雪松木采油方法也使用更复杂的反应器系统。因此,快速热解可以提供具有成本效益的途径,利用东方红杉树。本文的目的是研究的热解操作条件,包括热解温度,气体流量和颗粒大小在生物油产量,生物油特性和碳转化效率使用东红色雪松作为生物质原料的影响。这项研究的目的是验证快速热解是利用东方红杉的有效方法。

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