A Mn(II) Metal-Organic Framework Constructed from a Tetrahedral Silicon-Cored Ligand

机译：由四面体硅芯配体构成的Mn（II）金属有机骨架

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A novel metal-organic framework, MnCl_2(BIPS)_2·2CH_3OH·2H_2O (1), was synthesized from MnCl_2 and a tetrahedral silicon-cored ligand, Me_2Si(p-C_6H_4-imdazol-1-yl)_2 (BIPS) under the slow diffusion method. The structure was determined by single-crystal X-ray diffraction. Complex 1 is a 2D sheet structure constructed from 1D chains with 34-atom metallamacrocycles.

机译：从MnCl_2和四面体硅芯配体，ME_2SI（P-C_6H_4-IMDAZOL-1-YL）_2（横向）（横向硅 - 芯配体中合成了一种新型金属 - 有机框架MnCl_2（横梁）_2·2CH_3OH·2H_2O（1）。慢速扩散方法。通过单晶X射线衍射确定该结构。复合体1是由1D链构造的2D片状结构，具有34-原子金属丙族。

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《International Conference on Applied Mechanics and Materials》|2013年||共4页
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Qing-Yu Ma; Rui-Fang Guan; Guo-Zhong Li; Deng-Xu Wang;
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中图分类 TB3-53;
关键词
Metal-Organic Frameworks; Silicon-Cored; Tetrahedral Ligands; Imidazole;

机译：金属有机框架;硅芯;四面体配体;咪唑;

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4. A Mn(II) Metal-Organic Framework Constructed from a Tetrahedral Silicon-Cored Ligand [C] . Qing-Yu Ma, Rui-Fang Guan, Guo-Zhong Li, International Conference on Applied Mechanics and Materials . 2013

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机译：两个混合配体配位聚合物的组装，其具有由M（II）离子构成的二维金属 - 有机框架，其中野生酸盐和1,2-双 - （4-吡啶基）乙烯（M = Cd和Zn）

A Mn(II) Metal-Organic Framework Constructed from a Tetrahedral Silicon-Cored Ligand

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