首页> 外文会议>Symposium in Honor of Digby D. Macdonald >Effect of Galvanostatic Condition on Growth Behavior and Repassivation Potential of Crevice Corrosion of Duplex Stainless Steels
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Effect of Galvanostatic Condition on Growth Behavior and Repassivation Potential of Crevice Corrosion of Duplex Stainless Steels

机译:镀锌条件对双相不锈钢缝隙腐蚀生长行为及回报潜力的影响

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The purpose of this study is to clarify effect of galvanostatic condition on growth behavior and repassivation potential (E_(r.crev)) of crevice corrosion of duplex stainless steels. E_(r.crev) measurements, microscopic observation of corroded area, and solution pH measurements inside crevice were carried out. Under the condition of large holding current in propagation step of E_(r.crev) measurements, the crevice corrosion grew from the bottom to the edge of crevice. Then, it grew towards depth direction, and the sharp corroded area formed near the edge of crevice. Solution pH inside crevice lowered easily under the condition of large holding current in repassivation step, and it induced the repassivation of corroding crevice at noble potential. It was suggested that the sharp corroded area formed near the edge of crevice under the large holding current condition contributed to lowering corrosivity of solution inside corroding crevice and the repassivation of corroding crevice at the noble potential.
机译:本研究的目的是阐明通过双相不锈钢的缝隙腐蚀的生长行为和重新分配潜力(E_(R.CREV))的曲面腐蚀。 e_(r.crev)测量,进行腐蚀区域的微观观察和缝隙内的溶液pH测量。在E_(R.CREV)测量的传播步骤中的大保持电流的条件下,缝隙腐蚀从缝隙的底部增加到缝隙边缘。然后,它朝向深度方向发展,并且在缝隙的边缘附近形成的尖锐腐蚀区域。溶液内缝隙内部的pH在重新分配步骤中大保持电流的条件下轻松降低,并且它引起了崇高电位腐蚀缝隙的回复。建议在大的保持电流条件下缝隙边缘形成的尖锐腐蚀区域有助于降低腐蚀缝隙内的溶液的腐蚀性以及腐蚀缝隙处的腐蚀缝隙处的腐蚀性。

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