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Experiments and Modeling of the Autoignition of Methyl-Cyclohexane at High Pressure

机译:高压下甲基环己烷自燃的实验与建模

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The autoignition delays of mixtures of methyl-cyclohexane (MCH), oxygen, nitrogen, and argon have been studied in a heated rapid compression machine under the conditions P_c = 50 bar, T_c = 690 - 910K. Three different mixture compositions were studied, with equivalence ratios ranging from Φ = 0.5 - 1.5. The trends of the ignition delay measured at 50 bar were similar to the trends measured in earlier experiments at P_c = 15.1 and 25.5 bar. The experimentally measured ignition delays were compared to a newly updated chemical kinetic model for the combustion of MCH. The model has been updated to include newly calculated reaction rates for much of the low-temperature chemistry. The agreement between the experiments and the model was substantially improved compared to a previous version of the model. Nevertheless, despite the encouraging improvements, work continues on further advances, e.g. in improving predictions of the first stage ignition delays.
机译:在P_C = 50巴的条件下,已经在加热的快速压缩机中研究了甲基环己烷(MCH),氧气,氮气和氩气混合物的自燃延迟.P_C = 690-910K。研究了三种不同的混合物组合物,其等当量比φ= 0.5-1.5。在50巴特测量的点火延迟的趋势类似于P_C = 15.1和25.5巴的早期实验中测量的趋势。将实验测量的点火延迟与用于MCH燃烧的新更新的化学动力学模型进行了比较。该模型已更新,以包括许多低温化学的新计算的反应速率。与先前版本的模型相比,实验与模型之间的协议显着提高。尽管如此,尽管有了令人鼓舞的改进,但工作继续进一步进展,例如,在提高第一阶段点火延迟的预测中。

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