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Indium Gallium Nitride on Germanium by Molecular Beam Epitaxy

机译:分子束外延上的锗铟氮化镓

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Indium containing Ill-Nitride layers are predominantly grown by heteroepitaxy on foreign substrates, most often Al_2O_3, SiC and Si. We have investigated the epitaxial growth of In_xGa_(1-x)N (InGaN) alloys on Ge substrates. First we looked at the influence of buffer layers between the InGaN and Ge substrate. When applying a high temperature (850 °C) GaN buffer, the InGaN showed superior crystal quality. Furthermore the influence of growth parameters on the structural quality and composition of InGaN layers has been looked into. For a fixed gallium and nitrogen supply, the indium beam flux was increased incrementally. For both nitrogen- as well as for metal (Ga + In) rich growth conditions, the In incorporation increases for increasing In flux. However, for metal rich growth conditions, segregation of metallic In is observed. An optimum in crystal quality is obtained for a metal:nitrogen flux ratio close to unity. The XRD FWHM of the GaN (0002) reflection increases significantly after InGaN growth. Apparently the presence of indium deteriorates the GaN buffer during InGaN growth. The mechanism of the effect is not known yet.
机译:含有不含氮化物层的铟主要通过异质缺陷种植对外底物,最常是Al_2O_3,SiC和Si。我们研究了GE底物上的in_xga_(1-x)n(IngaN)合金的外延生长。首先,我们研究了IngaN和Ge衬底之间的缓冲层的影响。当施加高温(850℃)GaN缓冲液时,IngaN显示出优异的晶体质量。此外,研究了生长参数对IngaN层的结构质量和组成的影响。对于固定镓和氮气供应,铟束通量逐渐增加。对于氮气以及金属(Ga + In)富生长条件,在助焊剂中增加增加。然而,对于金属富含生长条件,观察到金属的偏析。为金属提供最佳的晶体质量:施氮量接近统一。 GaN(0002)的XRD FWHM在IngaN生长后的反射增加显着增加。显然,铟的存在在IngaN生长期间恶化了GaN缓冲液。效果的机制尚未知道。

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