首页> 外文会议>Radtech International UV and EB Curing Technology Exposition and Conference >RADIOLYTIC DEGRADATION OF HUMIC ACID: AN ALTERNATIVE TO COMPLEMENT THE CHEMICAL TEST OF WATER RESOURCES
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RADIOLYTIC DEGRADATION OF HUMIC ACID: AN ALTERNATIVE TO COMPLEMENT THE CHEMICAL TEST OF WATER RESOURCES

机译:腐殖酸的辐射性降解:补充水资源化学试验的替代方案

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The process of the radiolytic degradation is a new method of mineralization by advanced oxidation of the water that can be applied for the removal of humic compounds in all water systems. However, the deep mineralization of dissolved humic acid requires very high absorbed doses (tens of kilograys) because of the aromatic nature of the main units of humic acid and the well-known chemical and biochemical stability of its molecules. The effects degradation and absorbed dose of humic acid present in an aqueous solution were investigated on a laboratory scale upon gamma-irradiation from a Co-60 and electron beam source, to assessment the efficiency of decreasing of humic acid presence. We are studying the absorbed doses required to remove 50% and 90% of initial humic acid concentrations in distilled water solutions. Current results show a significant improvement the effectiveness of radiolytic degradation. Gamma-irradiation and electron beams are being used out in distilled water solutions. We are checking decolorization of naturally occurring in degraded at low absorbed doses in distilled water solutions (dilute humic acid solutions) and in occurring precipitation. Additionally, chemical analysis of the total organic carbon (TOC) which is one of the products degradation by irradiation and UV-visible spectroscopic changes were also evaluated by the parameters relating to the concomitant removal of the total organic carbon as well as by the ratios using absorption values at discrete wavelengths.
机译:辐射性降解的方法是通过高级氧化水的矿化方法,其可用于去除所有水系统中的腐殖质化合物。然而,溶解的腐殖酸的深度矿化需要非常高的吸收剂量(几十千龙),因为腐殖酸的主要单位和其分子的众所周知的化学和生化稳定性的芳香性质。在来自CO-60和电子束源的γ-辐射后,研究了在水溶液中存在的腐殖酸中存在的腐殖酸的效果和吸收剂量,以评估腐殖酸存在下降的效率。我们正在研究所需的吸收剂量,以除去蒸馏水溶液中的50%和90%的初始腐殖酸浓度。目前的结果表明,放射性降解的有效性显着提高。在蒸馏水溶液中使用伽马辐照和电子束。在蒸馏水溶液(稀腐殖酸溶液)和发生的沉淀中,检查在低吸收剂量的低吸收剂量的天然发生的脱色。另外,通过辐射和UV可见光谱改变的总有机碳(TOC)的化学分析也通过与伴随总有机碳以及使用的比率相关的参数评估离散波长的吸收值。

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