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The Catalysis of 3, 8-Substituted Cobalt (II) Deuteroporphyrin Dimethyl Esters to the Oxidation of Cyclohexane by Air

机译:3,8-取代的钴(II)氘代卟啉二甲酯的催化分析到空气中环己烷的氧化

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摘要

A variety of 3, 8-substituted cobalt (II) deuteroporphyrin dimethyl esters were synthesized and used as catalysts in the oxidation of cyclohexane. The effect of substituents on catalytic activities of 3, 8-substituted cobalt (II) deuteroporphyrin dimethyl esters were investigated. The results showed that the catalytic activities were influenced by the electron effects and steric effects of substituents and the thermal stability of catalysts.
机译:合成各种3,8取代的钴(II)氘代卟啉二甲基酯,并用作环己烷氧化的催化剂。研究了取代基对3,8取代的钴(II)氘卟啉二甲酯的催化活性的影响。结果表明,催化活性受到代效的电子效果和催化剂的热稳定性的影响。

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