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Recycling of thermosetting epoxy molding compound waste into PVC composites: effect of silane coupling agent on Morphology and Physical Properties

机译:热固性环氧模塑复合废物回收PVC复合材料:硅烷偶联剂对形态和物理性质的影响

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The aim of this study was to investigate the recycling of waste cured epoxy molding compound (c-EMC) which was generated as the mold residue in molding process of electronic component packages, by way of blending the pulverized mold residue with poly (vinyl chloride) (PVC) and other additives to prepare a reproduction composite. The influence of modified and non-modified c-EMC powder on structure and properties of the composites were analyzed by mechanical tests, vicat softening point test (VST) and scanning electron microscopy (SEM). The results showed that simple adding c-EMC powder could improve the stiffness and heat resistance of the composites, though decreased the mechanical strength of the composites. After being pretreated by silane coupling agent γ-aminopropyltriethoxysilane (KH-550), modified c-EMC powder had effective strengthening and toughening effects on the composites with the increasing powder content. Furthermore, better interfacial adhesion and higher VST value of the composites were observed in the presence of KH-550.
机译:本研究的目的是研究废物固化的环氧模塑化合物(C-EMC)的回收,其通过将粉碎的模渣与聚(氯乙烯)混合而产生的模具残留物。 (PVC)和其他添加剂制备再现复合材料。通过机械试验,VICAT软化点试验(VST)和扫描电子显微镜(SEM)分析改性和未修饰的C-EMC粉末对复合材料结构和性质的影响。结果表明,简单的添加C-EMC粉末可以改善复合材料的刚度和耐热性,但减少了复合材料的机械强度。通过硅烷偶联剂γ-氨基丙基三乙氧基硅烷(KH-550)进行预处理后,改性的C-EMC粉末在随着粉末含量增加的复合材料上具有有效的强化和增韧效果。此外,在KH-550的存在下观察到复合材料的更好的界面粘附和较高的VST值。

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