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On-Site Sampling at Industrial Fluid Catalytic Cracking Strippers and Laboratory-Scale Experiments on Chemical Stripping

机译:工业液催化裂化剥离器的现场抽样和化学剥离的实验室规模实验

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On-site sampling at industrial fluid catalytic cracking (FCC) plants was performed using a specially designed sampling apparatus. Catalyst and hydrocarbon samples were analyzed. Light hydrocarbons with high volatility are directly entrained out of the stripper by steam, but the high chemical reactivity of hydrocarbons plays a key role in improving the stripping efficiency. The reduction of the amount of soft coke over the catalyst clearly minimizes coke yield, thereby yielding the maximum amount of desirable products. About 23—25 wt % of the products recovered from industrial strippers were investigated. Comparative lab-scale experiments on physical and chemical stripping were also carried out; In the presence of a regenerated catalyst, chemical stripping produces a higher yield of desirable products and less coke at a shorter stripping time. However, the ratio of regenerated catalyst-to-spent catalyst should be optimized to obtain a satisfactory result for an excessive amount of regenerated catalyst leading to hydrocarbon overcracking, which, is not beneficial to the decrease in coke yield.
机译:使用专门设计的采样装置进行工业流体催化裂化(FCC)植物的现场抽样。分析催化剂和烃样品。具有高挥发性的轻质碳氢化合物通过蒸汽直接夹带脱衣器,但烃的高化学反应性在提高剥离效率方面发挥着关键作用。催化剂上柔软焦炭量的减少显然最大限度地减少了焦炭产率,从而产生最大量的理想产品。研究了从工业剥离者恢复的23-25重量%的产物。还进行了对比较的实验室规模的物理和化学剥离实验;在再生催化剂存在下,化学剥离在较短的剥离时间下产生更高的理想产物的产率和更少的焦炭。然而,应优化再生催化剂与废催化剂的比例,以获得过量的再生催化剂的令人满意的结果,导致烃覆盖的烃,这与焦炭产量的降低没有有益。

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