The mechanical properties of low cis-butadiene modified HIPS

摘要

In this paper, low cis-butadiene (LCPB) is used in the process of polymerization of HIPS to study the influence of the polymerization condition on the particle size of rubber and mechanical property. It can be discovered from the study that the particle size was increased from 300nm to 500nm with the decreasing stir. The test of mechanical property shows that with the increase of content of rubber, elongation at break and impact strength on cantilever increase, but stretching strength decreases. On condition of 100 rpm, when the content of rubber increases from 3% to 9%, elongation at break increases from 21.9% to 25.0%, stretching strength decreases from 30.5 MPa to 23.9 MPa, and the cantilever impact strength increases from 5.4KJ/m~2 to 9.3KJ/m~2. On condition of 200 rpm, when the content of rubber increases from 3% to 9%, elongation at break increases from 21.4% to 29.1%, stretching strength decreases from 28.7 MPa to 20.8 MPa, and the cantilever impact strength increases from 5.2KJ/m~2 to 8.1KJ/m~2.