Oxidative Removal of Dibenzothiophene by H_2O_2 over Activated Carbon-supported Phosphotungstic Acid Catalysts

摘要

Phosphotungstic acid (HPW) supported on activated carbon (AC) combined with hydrogen peroxide formed an oxidative desulfurizaiton (ODS) system to oxidize sulfur-containing compounds in diesel fuel. Dibenzothiophene (DBT) dissolved in n-octane was selected as a model feedstock for studying this new ODS system. The HPW/AC catalysts were characterized with XRD, FTIR and N_2 adsorption-desorption measurements. HPW was highly dispersed on the surface of carbon support. It was found that the DBT adsorption capacity decreased from 42 mg S/g to 33.13 mg S/g as HPW loading amount increased from 0 to 15 wt.%. Oxidative removal of DBT in the model oil significantly increased with increasing HPW loadings on the support from 0 to 10 wt.%. 100% DBT was removed by using the catalysts with HPW content higher than 10 wt.%. At 80°C, oxidative removal of DBT reached 100% after 40 min of reaction when O/S molar ratio ranged from 4 to 10.