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Influence of Pyrrole Concentration on Cracking Activity of n-hexane in a Performance FCC Catalyst and Additives

机译:吡咯浓度对性能FCC催化剂和添加剂中正己烷裂化活性的影响

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To enhance the refinery margins there is always pressure to process different types of crude containing nitrogen and sulfur. Nitrogenous and sulfur compounds have adverse effects on the performance of catalytic processes. Studies on the effect of sulfur on catalyst and their removal through catalytic treatment have been reported. Whereas systematic study on the performance of FCC catalysts and additives in presence of nitrogenous compounds is not well understood. This topic deals with studies on effect of model nitrogen compounds like pyrrole (non-basic) on the performance of fluid catalytic cracking catalyst and additives. And we have also study the effect of concentration of nitrogen compounds on cracking activity of n-hexane and VGO, the reasons for the deactivation of the catalysts seems to be due to deactivation of active sites by the strong adsorption of nitrogen compounds Alkali-treated ZSM-5 zeolites produce higher yields of light olefins compared to either untreated zeolites or alkali-treatment introduces mesopores to the zeolites and improves their catalytic cracking ability.
机译:为了增强炼油厂利润,总有压力来处理含有氮和硫的不同类型的原油。含氮和硫化合物对催化过程的性能具有不利影响。据报道了研究硫对催化剂对催化剂的影响及其通过催化处理的去除。虽然对含氮化合物存在的FCC催化剂和添加剂的性能系统研究尚不清楚。本课题涉及研究吡咯(非基本)如吡咯(非基本)对流体催化裂化催化剂和添加剂的效果的研究。并且我们还研究了氮化合物浓度对正己烷和vgo的裂化活性的影响,催化剂失活的原因似乎是由于活性位点通过强吸附的氮化合物碱处理ZSM的激活而失活-5沸石产生的轻质烯烃产量更高相比未处理沸石或碱处理介绍中孔的沸石和改善它们的催化裂化能力。

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