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Deterioration Characteristic of Catalyzed DPF Applied on Diesel Truck Durable Ageing

机译:催化DPF施加柴油耐用老化的劣化特性

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In this paper, it was researched the degradation characteristics of catalytic performance of three kinds of DPFs (C1, C2 and C3, with precious metal concentrations being 15, 25 and 35 g/ft3 respectively) after diesel truck aging. It is found out that the crystallinity of three kinds of DPF samples (Used) in full vehicle aging was higher than that of fresh samples (Fresh) and aged samples (Aged) in the laboratory. Compared with Fresh samples, the concentration of Pt atom in precious metal on the surface of Aged and Used samples tends to decrease in most cases. Activities to CO and C3H8 of Aged and Used samples of three kinds of DPFs had all been degraded, and activity degradation showed a substantial correlation with concentration reduction rate of precious metal on the carrier surface. NO_2 productivity of Used samples all rose. Crystallinity of DPF samples after full vehicle aging in Inlet, Middle and Outlet areas successively increased. The reduction rate of Pt atom concentration of Inlet samples was higher, followed by that of Outlet layer samples, and that of Middle layer samples was lower. Activities to CO, C3H8 and NO_2 of Inlet samples were relatively low, yet the catalytic activity of Middle samples was relatively high. Activity differences were resulted from the differences of thermal degradation due to different thermal loads during aging.
机译:本文研究了柴油卡车老化后,研究了三种DPFS(C1,C2和C3的催化性能的降解特征,贵金属浓度为15,25和35克/富富3)。发现全载体老化中的三种DPF样品(使用)的结晶度高于实验室中新鲜样品(新鲜)和年龄样品(年龄)。与新鲜样品相比,在大多数情况下,老化和使用样品表面上贵金属的Pt原子的浓度趋于降低。对于三种DPF的老化和使用样品的CO和C3H8的活动得到了降级,并且活性降解与载体表面上贵金属的浓度降低速率显着相关。 NO_2所用样品的生产力全部玫瑰。在入口,中间和出口区域的全车载衰老后DPF样品结晶性。入口样品的PT原子浓度的减少率较高,然后是出口层样品的样品,中间层样品的样品较低。进样样品的CO,C3H8和NO_2的活性相对较低,但中间样品的催化活性相对较高。由于在老化期间由于不同的热负荷而导致热降解的差异导致活性差异。

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