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Catalytic activity of iridium NHC complexes covalently bonded to carbon nanotubes and graphene oxide

机译:铱NHC络合物的催化活性与碳纳米管和氧化碳烯烃共价键合

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Carbon nanotubes and graphene have been extensively applied as proactive supports to generate heterogeneous catalysts. Both exhibit a carbon structure composed by carbon atoms with sp2 hybridization and both are used in similar applications, as in catalysis. However, the role of each particular substrate, determined by its structural peculiarities, can be differentvshould be studied for each particular catalytic reaction and in their structure.The aim of this work is to study the differences between oxidized carbon nanotubes (CNT) and graphene oxides (GO) as proactive supports of iridium N- heterocyclic carbene (NHC) catalyst. The effect of their inherent structure in the catalytic activity in hydrogen transfer reactions was studied in detail.
机译:碳纳米管和石墨烯已被广泛地施加为基质载体以产生非均相催化剂。 两者都表现出由SP2杂交的碳原子组成的碳结构,两者都用于类似的应用,如催化剂中。 然而,通过其结构特异性确定的每个特定基材的作用可以是不同的vshould用于每个特定的催化反应和它们的结构。这项工作的目的是研究氧化碳纳米管(CNT)和石墨烯氧化物之间的差异 (GO)作为铱N-杂环卡宾(NHC)催化剂的主动支持。 详细研究了它们固有结构在氢转移反应中催化活性的影响。

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