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INTERACTION BETWEEN GRAPGITE OXIDE NANOPARTICLES AND FUNCTIONALIZED MOLECULES: A WAY TO PRODUCE AND/OR STABILIZE GRAPHENE COATINGS

机译:氧化钛氧化物纳米颗粒与官能化分子之间的相互作用:生产和/或稳定石墨烯涂层的方法

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Graphite oxide (GO) is an accepted precursor to produce graphene membranes and coatings. GO can be restored to graphite either by physical processing (microwave irradiation, laser or thermal treatment), or by chemical way with reducing agents (ascorbic acid, hydrazine, etc.). In the case of a thin coating of GO, graphene layers are produced. The process of graphene formation from GO is crucial for the quality of new-formed graphene layer. Commonly, the graphene sheets formed after physical or chemical treatment, are stacked more or less disorderly, resulting in significant decrease in quality of the coatings. To solve this problem we used the additives of organic molecules, namely, Congo red (CR), containing reactive functional groups that can interact wim the functional groups of GO nanoparticles and fuse them together. Structure of CR depends on the pH of solution (Fig. 1).
机译:石墨氧化物(GO)是产生石墨烯膜和涂层的预见前体。通过物理处理(微波辐照,激光或热处理)或通过化学方式可以通过降低药剂(抗坏血酸,肼等)来恢复石墨。在GO薄涂层的情况下,生产石墨烯层。从Go的石墨烯形成过程对于新成型的石墨烯层的质量至关重要。通常,物理或化学处理之后形成的石墨烯片或多或少无序堆叠,导致涂层的质量显着降低。为了解决这个问题,我们使用了有机分子的添加剂,即刚果红色(Cr),含有可以相互作用的反应性官能团,其纳米颗粒的官能团并将它们熔化在一起。 CR的结构取决于溶液的pH(图1)。

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