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Rheological Investigation of Highly Filled Polymers: Effect of Molecular Weight

机译:高度填充聚合物的流变研究:分子量的影响

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The paper deals with rheological properties of highly filled polymers used in powder injection molding. Within the experimental framework seven PIM feedstocks based on superalloy Inconel 718 powder were prepared. Each feedstock contains the fixed amount of powder loading and the same composition of binder system consisting of three components: polyethylene glycol (PEG) differing in molecular weight, poly (methyl methacrylate) (PMMA) and stearic acid (SA). The aim is to investigate the influence of PEG's molecular weight on the flow properties of feedstocks. Non-Newtonian indices, representing the shear rate sensitivity of the feedstocks, are obtained from a polynomial fit, and found to vary within measured shear rates range from 0.2 to 0.8. Temperature effect is considered via activation energies, showing decreasing trend with increasing of molecular weight of PEG (except of feedstock containing 1,500 g.mol~(-1) PEG).
机译:本文涉及用于粉末注射成型的高填充聚合物的流变性能。在实验框架内,制备了基于超合金Inconel 718粉末的7 PIM原料。每种原料含有固定量的粉末负载量和由三种组分组成的相同组成:分子量不同,聚(甲基丙烯酸甲酯)(PMMA)和硬脂酸(SA)不同的聚乙二醇(PEG)。目的是探讨PEG分子量对原料流动性质的影响。非牛顿指数,代表原料的剪切速率灵敏度是从多项式配合获得的,并且发现在测量的剪切速率范围内变化,范围为0.2至0.8。通过活化能量考虑温度效应,显示佩格的分子量的降低趋势(除了含有1,500g.mol〜(-1)PEG的原料除外)。

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