SYNTHESIS OF CARBONIC-NICKEL NANOSTRUCTURESAND THEIR APPLICATION FOR PROTON PUMPS

摘要

High porous carbon material was prepared by template synthesis. Ni-carbonmaterials were formed by deposition of Ni2+ salts into the carbon supporter pores andby following reducing of adsorbed Ni2+ to Ni. The structure peculiarities of nickel—carbon materials were studied by small-angle X-ray scattering methods. Obtaining Ni-carbon materials used as electrodes in proton pump were enabled to raise its power andto reduce the price. The Ni-nanocarbon electrodes in proton pump have shown the highcatalytic activity in electrode processes of hydrogen ionization. It was demonstrated theinfluence of proton current on the rate of some catalytic reactions such as propenehydration, isopropyl alcohol dehydration, synthetic gas to dimethyl ether conversionand isopropylbenzene hydrocracking. The use of Ni-carbon nanostructured materials aselectrodes and proton current increases essentially the hydrogenating function ofindustrial catalysts in isopropylbenzene hydrocracking process.