Application of Cryo Scanning Electron Microscopy and In Situ X-Ray Diffraction for the Investigation of Early Time Portland Cement Hydration

摘要

Advanced preparation techniques open new ways for SEM and X-ray diffraction (XRD) investigations on hydrating cementitious systems. In this paper the early time hydration of Portland cement is studied with advanced cryo scanning electron microscopy techniques in combination with in situ X-ray diffraction and heat-flow calorimetry. The application of preparation techniques and analytical methods to Portland cement hydration are presented and discussed. Some aspects of hydration reactions are focused. The reaction products of the first minutes, changes in ettringite morphology, AFm formation during the deceleration period and the visualisation of C-S-H microstructures were special points of interest.