OLEFIN METATHESIS MEDIATED BY: - SCHIFF BASE Ru-ALKYLIDENES - Ru-ALKYLIDENES BEARING UNSYMMETRICAL NHC LIGANDS

机译：烯烃复分解介导的： - 席克夫碱Ru-烷基 - Ru-烷基含有非对称NHC配体的Ru-烷基

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The classic Grubbs second-generation complex 2 was modified through 1. The introduction of a bidentate Schiff base ligand 2. Changes in the amino side groups of the NHC ligand Representative olefin metathesis test reactions show the effects induced by the ligand modifications and demonstrate some interesting new properties of the described catalysts. catalysts.

机译：经典的Grubbs第二代综合体2通过1.引入二齿席夫碱配体2. NHC配体代表性烯烃复分解试验反应的氨基侧组的变化显示了配体修饰诱导的效果，并证明了一些有趣的效果所述催化剂的新性质。催化剂。

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《NATO Advanced Study Institute on Metathesis Chemistry: From Nanostructure Design to Synthesis of Advanced Materials》|2007年||共2页
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作者
STIJN MONSAERT; NELE LEDOUX; BART ALLAERT; RENATA DROZDZAK; PASCAL VAN DER VOORT; FRANCIS VERPOORT;
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正文语种
中图分类工程材料一般性问题;
关键词
olefin metathesis; ruthenium; asymmetrical N-heterocyclic carbene; schiff-base; alkylidene; DCPD;

机译：烯烃复分解;钌;不对称的N-杂环碳切菜;Schiff-base;烷基;DCPD;

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专利

1. Specialized Ruthenium Olefin Metathesis Catalysts Bearing Bulky Unsymmetrical NHC Ligands: Computations, Synthesis, and Application [J] . Malecki Pawel, Gajda Katarzyna, Gajda Roman, ACS catalysis . 2019,第1期

机译：含有大件不对称NHC配体的专用钌烯烃复分解催化剂：计算，合成和应用
2. Cycloalkyl-based unsymmetrical unsaturated (U_2)-NHC ligands: flexibility and dissymmetry in ruthenium-catalysed olefin metathesis [J] . Mathieu Rouen, Etienne Borré, Laura Falivene, Dalton transactions: An international journal of inorganic chemistry . 2014,第19期

机译：基于环烷基的不对称不饱和（U_2）-NHC配体：钌催化的烯烃复分解中的柔性和不对称性
3. Olefin Metathesis Catalyst Supported by a Hemilabile NHC Ligand Bearing Polyether Arms: Structure, Activity, and Decomposition [J] . Carter Jordan D., Schrodi Yann Organometallics . 2020,第3期

机译：由血管NHC配体轴承聚醚臂的烯烃复分解催化剂：结构，活性和分解
4. OLEFIN METATHESIS MEDIATED BY: - SCHIFF BASE Ru-ALKYLIDENES - Ru-ALKYLIDENES BEARING UNSYMMETRICAL NHC LIGANDS [C] . STIJN MONSAERT, NELE LEDOUX, BART ALLAERT, NATO Advanced Study Institute on Metathesis Chemistry: From Nanostructure Design to Synthesis of Advanced Materials . 2007

机译：烯烃复分解介导的： - 席克夫碱Ru-烷基 - Ru-烷基含有非对称NHC配体的Ru-烷基
5. Ruthenium-based olefin metathesis catalysts bearing pH-responsive ligands: External control of catalyst solubility and activity [D] . Balof, Shawna Lynn 2011

机译：带有pH响应配体的钌基烯烃复分解催化剂：催化剂溶解度和活性的外部控制
6. Ruthenium-based olefin metathesis catalysts with monodentate unsymmetrical NHC ligands [O] . Veronica Paradiso, Chiara Costabile, Fabia Grisi 2018

机译：具有单齿不对称NHC配体的钌基烯烃复分解催化剂
7. Novel Olefin Metathesis Ruthenium Catalysts Bearing Backbone- Substituted Unsymmetrical NHC Ligands [O] . Veronica Paradiso, Valerio Bertolasi, Fabia Grisi 2014

机译：含有骨架的新型烯烃复分解钌催化剂 - 取代的不对称NHC配体

OLEFIN METATHESIS MEDIATED BY: - SCHIFF BASE Ru-ALKYLIDENES - Ru-ALKYLIDENES BEARING UNSYMMETRICAL NHC LIGANDS

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